화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 기능성 고분자
제목 Application of ultrathin polypyrrole nanosheets (UPNSs) as a counter electrode for dye-sensitized solar cell
초록 The counter electrode (CE) in the dye-sensitized solar cells (DSSCs) plays a role in regenerating the oxidized sensitizer through the reduction of the redox species after electron injection. Due to the high conductivity and electro-chemical stability, conducting polymers have the potential to replace platinized counter electrodes in DSSCs. Among them, polypyrrole (PPy) is of special interest because of its easy and fast synthesis, high conductivity, electrochemical reversibility and environmental stability. UPNSs were fabricated by soft template polymerization method using Sodium Decylsulfonate(SDSn) hydrate crystal in aqueous medium. The UPNSs were coated onto fluorine-doped tin oxide (FTO) substrate to use as CE in DSSCs. The performance of the PPy-based DSSCs was characterized by cyclic voltammetry, current density-voltage measurements and electrochemical impedance spectroscopy.
저자 황동기, 임승순
소속 한양대
키워드 dye sensitized solar cell; DSSC; Counter electrode; CE; Pyrrole; Polypyrrole
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