화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 Graphene-Polymer Hybrids for Energy and Environmental Applications
제목 Edge-Selectively Functionalized Graphite
초록 We demonstrate efficient and eco-friendly methods for the scalable synthesis of low-cost and high-quality graphene. The approach involves edge-selective functionalization of graphite as a precursor for graphene via a “direct” covalent attachment of organic molecular wedges and/or functional groups to the edges of pristine graphite. The approach is the first case of “direct” functionalization of pristine graphite. Unlike graphite/graphene oxide (GO), it is an important step toward high-yield exfoliation of three-dimensional graphite into two-dimensional graphene nanosheets without basal plane distortion. The resultant edge-selectively functionalized graphite is readily dispersible in common organic solvents with high concentration. The improved dispersibility is driven by a strong interaction between the wedges and/or functional groups on graphite edges and the corresponding solvent.
저자 백종범
소속 울산과학기술대
키워드 Graphene; Graphite; Edge-Functionalization
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