학회 |
한국고분자학회 |
학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
권호 |
37권 1호 |
발표분야 |
Graphene-Polymer Hybrids for Energy and Environmental Applications |
제목 |
Edge-Selectively Functionalized Graphite |
초록 |
We demonstrate efficient and eco-friendly methods for the scalable synthesis of low-cost and high-quality graphene. The approach involves edge-selective functionalization of graphite as a precursor for graphene via a “direct” covalent attachment of organic molecular wedges and/or functional groups to the edges of pristine graphite. The approach is the first case of “direct” functionalization of pristine graphite. Unlike graphite/graphene oxide (GO), it is an important step toward high-yield exfoliation of three-dimensional graphite into two-dimensional graphene nanosheets without basal plane distortion. The resultant edge-selectively functionalized graphite is readily dispersible in common organic solvents with high concentration. The improved dispersibility is driven by a strong interaction between the wedges and/or functional groups on graphite edges and the corresponding solvent. |
저자 |
백종범 |
소속 |
울산과학기술대 |
키워드 |
Graphene; Graphite; Edge-Functionalization
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E-Mail |
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