화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터)
권호 14권 2호
발표분야 촉매
제목 Functionalized Ionic Liquids Grafted on Silica: Heterogeneous Catalyst for Cycloaddition Reaction
초록 A series of ionic liquids functionalized by carboxyl group and hydroxyl group were synthesized and grafted on silica gel. The catalytic activity of heterogeneous catalysts for the synthesis of cyclic carbonate via cycloaddition reaction of epoxide and CO2 was studied. The effects of grafted ionic liquids structure and reaction conditions have been investigated. It was demonstrated that the synergetic effects of carboxylic acid moieties and halide anion in the catalyst were responsible for the high yield of cyclic carbonates and selectivity could be obtained at the optimized condition.
저자 한리나, 최수진, 박문석, 박대원
소속 부산대
키워드 Ionic liquids; Cycloaddition reaction; Epoxide; CO2
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