학회 |
한국고분자학회 |
학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
권호 |
39권 1호 |
발표분야 |
기능성 고분자 |
제목 |
Preparation of Fe3O4-Embedded Poly(styrene)/Poly(thiophene) Core/Shell Nanoparticles and Their Hydrogel Patterns for Sensor Applications |
초록 |
This research describes the preparation and sensor applications of multifunctional monodisperse, Fe3O4 nanoparticles-embedded poly(styrene)/poly(thiophene) (Fe3O4-PSt/PTh), core/shell nanoparticles. Monodisperse Fe3O4-PSt/PTh nanoparticles were prepared by free-radical combination (mini-emulsion/emulsion) polymerization for Fe3O4-PSt core and oxidative seeded emulsion polymerization for PTh shell in the presence of FeCl3/H2O2 as a redox catalyst, respectively. For applicability of Fe3O4-PSt/PTh as sensors, Fe3O4-PSt/PTh-immobilized poly(ethylene glycol) (PEG)-based hydrogels were fabricated by photolithography. The hydrogel patterns showed a good sensing performance under different H2O2 concentrations. They also showed a quenching sensitivity of 1 μg/mL for the Pd2+ metal ion within 1 min. The hydrogel micropatterns not only provide a fast water uptake property but also suggest the feasibility of both H2O2 and Pd2+ detection. |
저자 |
김용석1, 이현종1, 파타카무리 고빈다이아1, 손우현1, 고원건1, 정인우2, 김중현1
|
소속 |
1연세대, 2경북대 |
키워드 |
polythiophene; nanoparticles; fluorescence; quenching; sensor; hydrogel pattern
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E-Mail |
jayhkim@yonsei.ac.kr |