| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전)) |
| 권호 |
33권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis and Characterization of A Polyurea Containing Oligoaniline Blocks |
| 초록 |
t-Butoxycarbonyl (t-BOC) substituted aniline heptamer diamine as a monomer with good solubility and well-defined structure was synthesized by palladium-catalyzed aromatic amination. The oligoaniline was polymerized with 1,6-diisocyanatohexane to produce a polyurea which had good solubility in common solvents. Thin films were cast from its chloroform solution. The t-BOC groups were removed by thermal treatment at 242 oC for 1 h under a nitrogen atmosphere, as confirmed by UV-Vis spectroscopy, FT-IR spectroscopy, and elemental analysis. Different absorption peaks were observed in UV-Vis spectra in various states such as t-BOC deprotected and acid doped states. Electrochemical properties were investigated by using cyclic voltammetry. |
| 저자 |
김택경1, 박지웅2
|
| 소속 |
1광주과학기술원, 2신소재공학과 / 분자레벨집적화기초연구사업단 |
| 키워드 |
aniline; polyurea
|
| E-Mail |
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