| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 |
28권 2호, p.110 |
| 발표분야 |
고분자 합성 |
| 제목 |
Polymerization of Propylene Oxideby Using Novel Nano-sized Multi-metal Cyanide (MMC) Catalysts |
| 초록 |
Double-metal cyanide (DMC) complexes are well-known catalysts for epoxide polymerization. As the catalysts do not significantly promote the isomerization of propylene oxide, polyethers having low unsaturation values and high molecular weight can be prepared, compared to potassium hydroxide-catalyzed polymerizations. Unfortunately, the DMC catalysts have some drawbacks as induction time of polymerization is too long, we modified them by controlling their size to nano range by applying reverse emulsion method. In addition, multi-metal catalysts were synthesized by utilizing the same technique. Polymerizations of propylene oxide were carried out using the highly active nano-sized multi-metal cyanide catalysts. High performance of the newly developed catalysts was demonstrated by comparing with conventional catalysts. |
| 저자 |
변승훈1, 김탁2, 이민주1, 하창식2, 김일1
|
| 소속 |
1부산대, 2초미세화학공정시스템연구센터 |
| 키워드 |
MMC; polyol
|
| E-Mail |
|
