| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Nanostructures of Star-shaped Polystyrene-block-poly(methyl methacrylate) Copolymer |
| 초록 |
Star-shaped polystyrene-block-poly(methyl methacrylate) copolymer (PS-b-PMMA) was synthesized by using α-cyclodextrin (α-CD) as a core of the star-shape. Hydroxyl groups in the α-CD were substituted with bromine by esterification and it was used for atom transfer radical polymerization. We found that the number of bromine substituted arms per one α-CD was higher than 16 measured by nuclear magnetic resonance and Matrix-assisted laser desorption/ionization. We controlled the molecular weight and block compositions of block copolymer. Those block copolymers were characterized by gel permeation chromatography and nuclear magnetic resonance. Morphology of Star-shpaed block copolymer was characterized by TEM and small angle X-ray scattering. We could find diverse nanostructures of star-shaped block copolymer. |
| 저자 |
장상신1, 김진곤2, 문홍철1, 배두식1, 곽종헌1
|
| 소속 |
1POSTECH, 2POSETCH |
| 키워드 |
star-shaped block copolymer |
| E-Mail |
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