화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터)
권호 17권 2호
발표분야 포스터-정밀화학
제목 Effects of Nitrogen Content on Electrochemical Behaviors of Polyacrylonitrile-Based Activated Carbon Nanofibers
초록 In this work, activated carbon nanofiber (ACNFs) electrodes with high double layer capacitance and good rate capability were prepared from polyacrylonitrile (PAN) nanofibers by optimizing the carbonization temperature prior to CO2 activation. The surface morphologies and structural characteristics of ACNFs were investigated by SEM and XRD, respectively. The content of nitrogen was determined by the analysis of XPS and EA. Textural properties of the ACNFs prepared were investigated by N2/77K adsorption isotherms. The nitrogen content could be easily tailored by controlling the carbonization temperatures. With increasing the carbonization temperatures, the porosity gradually increased, while the nitrogen content decreased. The carbonization temperature has a marked effect on both the pore structure, and the electrochemical performances of the ACNFs.
저자 이혜민1, 김홍건2, 김병주1, 안계혁1
소속 1한국탄소융합기술원, 2전주대
키워드 polyacrylonitrile; carbonization temperature; electric double layer capacitor; CO2 activation
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