화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터)
권호 20권 1호, p.43
발표분야 고분자
제목 Preparation and characterization of poly(methyl methacrylate) derivatives having self-healing properties through the thermally reversible Diels-Alder reaction.
초록 In this study, we synthesized the furan-functionalized copolymer for self-healing materials. The furan monomer(furoyl ethyl ether methacrylate, FEEMA) obtained from the reactions between furoyl chloride and 2-hydroxy ethyl methacrylate was copolymerized with ethylene glycol methyl ether methacrylate (EGMA) with various feed ratio to show the effect of furan group on self-healing property.
Also 1,1'-(methylenedi-4,1-phenylene)bismaleimide is used as a cross-linker for thermally reversible Diels-Alder reaction. The stable film could be obtained within the specific range of ratio between furan group in copolymer and crosslinker, which shows the self-healing property.
저자 변금섭1, 최소원1, 최원재2, 이종찬2, 차상호1
소속 1경기대, 2서울대
키워드 free radical polymerization; self-healing; re-mendable; furan; Diels-Alder reaction
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