| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Effects of OLS containing Poly(styrene-ran-(4-vinylpyridine)) on Rheological Properties of Polystyrene Nanocomposite |
| 초록 |
We have designed the polymeric modifier free from critical problem such as compatibility and thermal property between organophilic layered silicates (OLS) and polystyrene (PS), and successfully developed a route to amine functionalized poly(styrene-ran-(4-vinylpyridine)). The morphology and thermal stability of the PS/OLS nanocomposites were studied by TEM and TGA. The PS nanocomposites showed better exfoliation and thermal properties, may be due to the control of surface characteristics of silicate, having affinity with the PS. The rheological properties for both oscillation and steady shear experiment indicated that the fabricated nanocomposite materials changed to solid-like as the OLS contents increased. Furthermore, the rheological properties of the nanocomposites were also investigated using a stress-controlled rotational rheometer under small amplitude oscillation and steady transient shear in the melt state. |
| 저자 |
한승산1, 박봉준2, 최형진2, 이재흥1, 김용석1
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| 소속 |
1한국화학(연), 2인하대 |
| 키워드 |
organophilic layered silicate (OLS); morphology; thermal stability; nanocomposite; rheological properties
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| E-Mail |
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