화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 고분자 합성
제목 Synthesis of Polycarbonates by Melt Polymerization
초록 Polycarbonate (PC) is an important engineering thermoplastic material with good mechanical and optical properties for various industrial applications. It can be produced by an interfacial phosgenation process and melt transesterification process. In recent years, the melt transesterification of PC with the starting materials 2,2-bis(4-hydroxyphenyl)propane (Bisphenol-A, BP-A) and diphenyl carbonate (DPC) is becoming more important, since it is regarded as an environmentally benign production technique. In the present work, the melt transesterification of polycarbonate (PC) by diphenyl carbonate (DPC) and 2,2-bis(4-hydroxyphenyl)propane (Bisphenol-A, BP-A) was studied in the absence of catalyst and high molecular weight polycarbonates were prepared. The effect of different reaction parameters namely, reaction temperature and reaction time was studied on the different properties of polycarbonate.
저자 바스카 이드게, 심종민, 이성구, 김용석, 이재흥
소속 한국화학(연)
키워드 bisphenol-A (BP-A); diphenyl carbonate (DPC); melt polymerization
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