화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 분자전자 부문위원회 II
제목 Organic solar cells using 6-(2-thienyl)-4H-thieno[3,2-b]indole (TTI) copolymer with PCE of 2.6%
초록 Bulk-heterojunction organic solar cells (BHJ OSCs) based on conjugated polymers have been received most attention because potential of being fabricated of flexible and light-weight substrates. Although polymers have been widely used to BHJ OSCs and achieved power conversion efficiencies (PCEs) over 10%. We synthesized alternating conjugated polymers, PTTIBT and PTTIMBI. 6-(2-thienyl)-4H-thieno[3,2-b]indole (TTI) which was modified from benzene ring to thiophene ring in carbazole moiety used for electron-rich unit and BT/MBI used for electron-deficient units. All of polymers have good solubility in common organic solvents . PTTIMBI has the lower band gap of 1.57 eV. Optical and electrochemical characterizations exhibit that polymers have proper energy diagram. The power conversion efficiencies of PTTIMBI show 2.60 %.
저자 서홍석, 김진우, 김동준, 정인아
소속 부산대
키워드 Bulk-heterojunction; organic solar cells
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