화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 가을 (10/27 ~ 10/28, 고려대학교)
권호 12권 2호, p.2290
발표분야 열역학
제목 Isobaric vapor-liquid equilibria, density and viscosity for the binary mixture of exo- and endo-tetrahydrodicyclopentadiene
초록 The exo isomer of tetrahydrodicyclopentadiene (exo-THDCPD) is the major component of the high-energy-density rocket fuel referred to as JP-10. The endo isomer (endo-THDCPD), which is the precursor of the exo isomer, is also present in JP-10 as a minor component. Despite of their importance, very little thermochemical information on the pure tricyclic isomers and their mixture is available in the literature.
In this work, isobaric vapor-liquid equilibrium data for the binary mixture of exo-THDCPD(1)+ endo-THDCPD(2) were measured by using recirculating still at 10, 30, 50, 70, 90 and 101.3kPa. The measured VLE data were correlated with common gE model equations. Additionally density and viscosity were also measured for the same binary mixture at 298.15 K with the help of digital vibrating tube densimeter and precision viscometer.
저자 황인찬1, 박소진1, 한규진1, 최명재2, 한정식3
소속 1충남대, 2한국화학(연), 3국방과학(연)
키워드 density; viscosity; binary; exo; endo
E-Mail sjpark@cnu.ac.kr
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