화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 고분자가공/복합재료
제목 Morphology effect affecting the thermoelectric properties of doped P3HT films
초록 Recently, thermoelectric polymers have been extensively studied for their potential applications in flexible, printable and low-cost thermoelectric generators. We prepared highly crystalline poly(3-hexylthiophene) (P3HT) films by wire-bar-coating. The effect of film thickness and crystallinity of the P3HT films were investigated in this study. The maximum values of Seebeck coefficient, electrical conductivity and power factor of the wire-bar-coated and doped P3HT films were measured to be 37.2 μV K-1, 254 S cm-1, 35.0 μW m-1K-2, respectively. Through this study, it was found that the optimized thermoelectric properties can be obtained by controlling the film thickness and polymer structure. Further, because the selection of the processing method and the type of conjugated polymers determines the final thermoelectric characteristics of the films, they should be considered carefully for future thermoelectric applications.
저자 장광석1, 조성윤1, 류주환2, 강영훈1, 유영재1, 홍천택1
소속 1한국화학(연), 2충남대
키워드 thermoelectric; seebeck; p3ht; crystallinity; film thickness
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