화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 Stretchable Polymer/Hybrid Materials and Devices for Wearable Optoelectronics
제목 Synthesis and Analysis of Phosphorescent Iridium(III) Complexes for Organic Light-emitting Diod
초록 Small and medium-sized OLED display market continues to grow, and especially OLED TV market of the world is growing rapidly. Therefore leading OLED technology has become more and more important. In this paper, we synthesized phosphorescent Iridium (III) complexes. The ligands of Iridium (III) complexes were synthesized by Suzuki coupling reaction. The ligands through changes in oxidative addition materials to get the red color were to study the appropriate Iridium (III) complexes. Oxidative addition materials were used such as 2-bromo-4-(trifluoromethyl) pyridine, 2-bromoisonicotinonitrile, 4-amino-2-bromopridine. Also dithieno[3,2-b:2’,3’-d]thiophen-2-yl boronic acid was used as organic borane. Iridium (III) complexes were synthesized by 2 steps of Nonoyama reaction. Ancillary ligand used acetylacetone. Iridium (III) complexes were measured by nuclear magnetic resonance(NMR), UV-visible spectroscopy and photoluminescence(PL).
저자 박상용, 신동명, 양보나
소속 홍익대
키워드 Organic Light-emitting Diod; Phosphorescent Iridium(III); Dopant
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