| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
콜로이드·계면화학_포스터 |
| 제목 |
Silicon-polyvinyl alcohol hybrid pervaporation membrane for dehydration of ternary mixtures comprising highly reactive epichlorohydrin |
| 초록 |
The membranes from hydrophilic polymer (PVA) and in organic cross linker tetra ethyl orthosilicate (TEOS) called Silicon- PVA hybrid membrane were prepared and employed in the pervaporation removal of water from the azeotropic water/isopropyl alcohol/ECH feed mixtures. At the final state of epoxy resin production process, the ECH/IPA/water remains along with final product, and the recovery of the ECH/IPA from the ternary mixture by the vacuum distillation is a very complex and energy consuming process. Therefore the Si-PVA hybrid membrane was used to pervaporative dehydration of water/isopropyl alcohol/ECH mixtures. FTIR characterization was technique was used to confirm the PVA and TEOS crosslinking reaction. In the pervaporation output with increased of the TEOS content in the PVA-TEOS hybrid membrane, the permeation flux was decreased from the 0.14 kg/m2h to 0.05 kg/m2h and separation factor remarkably increased from 2099 to 13320 were observed. |
| 저자 |
Shivshankar Chaudhari1, 이남규1, 권용성2, 문명준1, 남승은2, 박유인2, 손민영1
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| 소속 |
1부경대, 2한국화학(연) |
| 키워드 |
Epichlorohydrin; Tetraethyl orthosilicate
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| E-Mail |
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