| 학회 |
한국고분자학회 |
| 학술대회 |
2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터) |
| 권호 |
44권 2호 |
| 발표분야 |
분자전자 부문위원회 II |
| 제목 |
Development of New Electro-Optic Ionic Crystals by Cationic Engineering with Halogen Substituents |
| 초록 |
We report on new electro-optic organic ionic crystals based on quinolinium electron acceptor-based cations having halogen substituents with aromatic anions. F1 crystals introducing with fluorine substituent on cation show identical crystal structure with non-halogenated analogous crystals. On the other hand, F1 crystals exhibit different THz spectral shape from non-halogenated analogous crystals, which resulted from newly created hydrogen bonds by fluorine substituents. Meanwhile, C1 and C2 analogous crystals introducing with other halogen substituents on cations show different crystal structure and increased π-π stacking distance compared to non-halogenated crystals. This change results in enhancement of macroscopic optical nonlinearity. |
| 저자 |
김세인1, 김원태2, 윤우진1, 윤호섭1, 이상민2, 권오필1
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| 소속 |
1아주대, 2KAIST |
| 키워드 |
Nonlinear Optics; Electro-Optics; Organic Crystals
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| E-Mail |
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