화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 액정/LCD 재료
제목 LIQUID CRYSTAL POLYMER ELECTROLYTES
초록 Ionic transport in typical polymer electrolytes is highly coupled to segmental motions of the polymer backbone which severely restricts cation mobility as the glass transition temperature is approached. One approach to overcome this limitation is to incorporate liquid crystallinity into the system. It is clear that the conductivity of these liquid crystal polymers does not “freeze out” as Tg is approached, but instead varies in an Arrhenius fashion over a temperature range inclusive of Tg. We will interpret this remarkable new pattern of behaviour in terms of activation volumes.
저자 Corrie T. Imrie
소속 Univ. of Aberdeen
키워드 Liquid Crystal; Polymer Electrolytes; Ionic Conductivity
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