| 초록 |
Zeolitic imidazolate frameworks (ZIFs) with tetrahedral Co metal cation have a characteristic porous structures as one of metal–organic frameworks (MOFs). Since the metallic cobalt nanoparticles have advantages such as lower RWGS activity and higher CO2 hydrogenation to light hydrocarbons, the adjustment of long chain hydrocarbons (C2 - C4 and C5+) was controlled by introducing iron, cupper and indium oxide on the MOF-derived catalysts in the present study. The adsorption strength of CO2 reactant and its different dissociated intermediates largely altered hydrocarbon distributions, which were confirmed by various surface characterization. |
