| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Synthesis and Characterization of New Ladder like Poly(silsesquioxane) Containing Polyoxazoline Moieties in the Side Chains. |
| 초록 |
We succeeded in the synthesis of new hybrid ladderlike poly(silsesquioxane) with polyoxazoline groups in the side chains. A reactive ladderlike poly(silsesquioxane) with pendant chloromethyl groups was used as an initiator for ring-opening polymerization of 2-methyl-2-oxazoline. The polymerization of 2-methyl-2-oxazoline was conducted with various feed ratios of 2-methyl-2-oxazoline to ladderlike poly(silsesquioxane). Their structures and thermal properties were investigated by H-NMR, IR, DSC, and TGA. The graft-shaped polymer consisting of a rigid-rod ladderlike poly(silsesquioxane) and hydrophilic poly(2-methyl-2-oxazoline) showed excellent thermal stability and good compatibility with commodity polymer. |
| 저자 |
안용철, 민병각, 임정혁, 김경민
|
| 소속 |
충주대 |
| 키워드 |
hybrid polymer; polyoxazoline
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| E-Mail |
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