학회 |
한국공업화학회 |
학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
권호 |
25권 2호 |
발표분야 |
포스터-콜로이드·계면화학 |
제목 |
Preparation of Tryptophan-terminated Double-hydrophilic Block-copolymer as a Preorganized Nanoscale Template for Functional Metal-Chelated Nanostructures |
초록 |
We present the preparation of tryptophan-terminated double-hydrophilic block-copolymer as a polymeric template for self-assembled nanostructures by a functional metal chelation. To compensate for the weak cohesive force of specific transition metal ions, the end group of the block-copolymer was modified with tryptophan, an amino acid containing a hydrophobic indole group, which also exhibits a characteristic fluorescence property. The resulting self-assembled polymeric nanostructure can then be used as a chelating template of the paramagnetic metal cations for the enhanced magnetic resonance contrasting effect in aqueous solution. |
저자 |
장유진, 이상민
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소속 |
가톨릭대 |
키워드 |
atom transfer radical polymerization; tryptophan; block-copolymers; nanoparticles
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E-Mail |
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