화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터)
권호 35권 1호
발표분야 기능성 고분자
제목 Comparison study of Poly(styrene sulfonic acid)-Gafted Fluoropolymer Membranes Prepared with Various Fluorinated Polymer Film
초록 In this study, poly(styrene sulfonic acid) was grafted onto FEP (Poly(tetrafluoroethylene-co-hexafluoropropylene)), PFA (Poly(tetrafluoroethylene-co-perfluorovinylether)), and ETFE (Poly(ethylene-co-tetrafluoroethylene)) by a simultaneous irradiation method using γ-rays. Several fluoropolymer membranes with similar DOG (degree of grafting) were prepared and subjected to a characterization study such as IEC (ion exchanging capacity), water uptake, proton conductivity, methanol permeability, and chemical stability. The results indicated that the ETFE based membrane showed a higher chemical stability than FEP and PFA based membranes. No significant differences in other characteristic properties were observed between the fluoropolymer membranes.
저자 고범석1, 강성아1, 경비1, 송주명2, 신준화2, 노영창2
소속 1전북대, 2한국원자력(연)
키워드 Irradiation; Fuel Cell; Membrane; Grafting
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