| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 봄 (04/25 ~ 04/27, 창원컨벤션센터) |
| 권호 |
24권 1호, p.860 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Direct CH4 carbonylation by CO2 to form acetic acid over BiOI catalyst |
| 초록 |
The development of efficient catalytic system for the direct synthesis of acetic acid from the carbonylation of CH4 by CO2 is significant for the potential utilization of these greenhouse gases. Herewith we demonstrate the BiOI as a promising catalyst for this reaction using H2O2 as an oxidant. At room temperature, CH4 carbonylation over BiOI catalyst was carried out using dimethyl sulfoxide as solvent and produced considerable acetic acid with high selectivity. From the general catalytic performance tests under various reaction conditions, BiOI displayed better performance compared to BiOIO3 and BiOI/BiOIO3 hetero structures which were tested as catalyst for comparison. This work was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF 2017R1D1A1B03036324). |
| 저자 |
Tatek Shiferraw Bezawit, Raghavendra Shavi, 서정길
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| 소속 |
명지대 |
| 키워드 |
촉매 및 반응공학 |
| E-Mail |
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| 원문파일 |
초록 보기 |
