| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
유기전자소자용 소재 및 소자(분자전자소재 부문위원회) |
| 제목 |
Synthesis of New Poly(thienylenevinylene) Derivatives with High Crystallinity and Charge-Carrier Mobility Exceeding 1 cm2V-1s-1 for Organic Thin-Film Transistors |
| 초록 |
Conjugated polymers have been attracting attention because of their suitability in a wide range of promising low-cost, flexible electronic applications such as organic thin-film transistors (OTFTs), organic photovoltaic cells (OPVs). We report synthesis and characterization of high performance p-channel conjugated polymers containing alkyl-substituted thienylenevinylene (TV) units as an active layer for OTFTs. Maximum charge-carrier mobility of PC6TV12T and PC12TV12T approached 0.47 and 1.05 cm2V-1s-1, respectively. The insertion of alkyl-substituted TV unit in the polymer backbone enabled a highly planar molecular structure and a high crystallinity in thin films as well as high solubility in common organic solvents. These polymers showed a very strong lamellar ordering up to fifth (500) order. Conjugated polymer-based complementary inverters with a high gain (~ 16) were successfully demonstrated by the inkjet printing of PC12TV12T (p-type) and N2200 (n-type). |
| 저자 |
김주환1, 임보규2, 백강준3, 노용영4, 정형구1, 윤진문1, 김동유1
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| 소속 |
1광주과학기술원 신소재공학부, 2스탠포드 대, 3한국전자통신(연), 4한밭대 |
| 키워드 |
Conjugated polymer; polymer semiconductor; organic electronics; OTFTs
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| E-Mail |
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