| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_환경·에너지 |
| 제목 |
마이크로파 연속반응기를 이용한 MIL-100(Fe) 합성 및 CO/CO2 흡착 분리 응용 |
| 초록 |
Metal-organic frameworks (MOFs), organic-inorganic hybrid crystalline materials with extreme structural diversity, are typically synthesized in closed batch systems which is not favorable for large-scale MOF synthesis. In this study, we tried a scalable MOF synthesis route based on a flow tubular reactor equipped with microwave volumetric heating. The system enabled continuous crystallization of MIL-100(Fe) with a high space time yield at relatively mild conditions as compared to conventional batch systems. The synthesized MIL-100(Fe) was used as a support to prepare Cu(I)-modified MIL-100(Fe) adsorbents. The Cu(I)@MIL-100(Fe) showed preferred CO adsorption over CO2. |
| 저자 |
Le Van Nhieu1, 공창인2, 김정훈2, 권혁택3, 김진수1
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| 소속 |
1경희대, 2한국화학(연), 3부경대 |
| 키워드 |
CO; CO2; adsorbent; MIL-100(Fe)
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| E-Mail |
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