화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2005년 봄 (04/22 ~ 04/23, 여수대학교)
권호 11권 1호, p.959
발표분야 촉매 및 반응공학
제목 Asymmetric ring opening of terminal epoxides catalyzed by bimetallic chiral (salen) Co complex via-hydrolytic kinetic resolution
초록 Epoxides are versatile building blocks for the organic synthesis and terminal epoxides are arguably the most important subclass of these compounds. In the present study kinetic resolution of terminal epoxides with water as nucleophile catalyzed by new readily synthesized bimetallic chiral (salen) Co complex provides practical method for their production in enantiomerically pure form.Reactions are conveniently carried out at ambient temperature under the air atmosphere.
저자 Thakur Santosh Singh, 김건중
소속 인하대
키워드 Asymmetric ring opening reaction; bimetallic chiral catalyst; terminal epoxides
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