| 초록 |
We investigated effect of compressibility and specific interaction on phase behaviors of homogeneous dendrimer solution using a compressible lattice cluster theory We examine the effect of compressibility on the phase behavior of dendrimer solutions with dendrimer generation number, number of bonds between two consecutive branch points along a chain and varying the strength of specific interaction among end-groups of dendrimer and solvent molecules. There is only slight change in LLE curve of dendrimer solutions for pressure. The critical temperature increases with decreasing a generation number and increasing a separator length. Our results show that the coexistence curve shows a great dependence on specific interactions and structure factors and rather small dependence on the compressibility. |
