| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 가을 (10/28 ~ 10/29, 건국대학교) |
| 권호 |
9권 2호 |
| 발표분야 |
촉매 |
| 제목 |
Oxidation of Adamantanone and Norcamphor over Tin Containing Mesoporous Moludular Sieves |
| 초록 |
It was shown that all types of catalysts, both Sn-MCM-41 exhibited conversions of adamantanone between 42-90 % and of norcamphor between 32-73% while Sn-MCM-48 exhibited conversions of adamntanone between 51-100% and conversion of norcamphor between 53-86%. In all reaction the selectivities to desired lactones were almost 100%. No direct relationship has been found between the conversions of individual ketons and bulk concentrations of tin in both Sn-MCM-41 and Sn-MCM-48. The Lewis sites accessible for pyridine measured by FT-IR spectroscopy do not probably participate in Baeyer-Villiger reaction to the same extent. |
| 저자 |
한상철1, I. Nekoksova2, 이영훈1, J. Cejka2, 박상언1
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| 소속 |
1인하대, 2Academy of Science of the Czech Republic |
| 키워드 |
Beayer-Villiger oxidation; Mesoporous; Tin;
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| E-Mail |
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