화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2020년 가을 (10/14 ~ 10/16, e-컨퍼런스)
권호 26권 1호, p.218
발표분야 미립자공학
제목 A Study on Silica Nanoparticles Grafted with Anionic Polyelectrolytes as Pickering Emulsifiers of Oil and High Salinity Aqueous Solutions
초록 Nanoparticles (NPs) may have great potential for various subsurface applications over the past decades. One of the important challenges for these applications is to achieve colloidal stability in subsurface media at high salinity and high temperature. It has been previously shown that NPs “multipoint”-grafted with anionic poly(AMPS-co-AA) exhibited remarkable colloidal stabilities in certain salinity such as API brine. However, many other important properties of such particles still remain unstudied. Herein, we investigate various properties of the silica (SiO2) NPs “multipoint”-grafted with poly(AMPS-co-AA) in NaCl and CaCl2 solutions. The brush behavior of the grafted random copolymers was investigated through wide range of salinities. The particles displayed brine-oil interfacial activity with increasing salt concentrations (Cs), stabilizing oil-in-brine emulsions. High internal phase emulsion (HIPE) could be formed in high Cs of CaCl2, which exhibited gel-like behavior.
저자 박현수1, 임세형1, 양지원1, 곽채수1, 김지은1, 최신식1, 김채빈2, 이주형1
소속 1명지대, 2부산대
키워드 미립자
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