화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-에너지저장·변환
제목 Synthesis and characterization of chiral squaraine dyes for optoelectronic applications
초록 Squaraines are a class of promising zwitterionic donor-acceptor-donor dyes for applications in optical sensing and imaging. Some attractive features of these dyes include strong absorption and emission bands which are tunable from the visible to near-infrared regime via molecular design and supramolecular engineering. Recently, there has been a growing interest in applying squaraine dyes in long-wavelength organic photodetectors. Extending this concept to chiroptical sensing is highly attractive due to its technological importance. However, chiral squaraine dyes with absorption in the near-infrared regime are still rare. To bridge this gap, this work aims to develop chiral squaraine dyes from a dicyanovinyl-substituted squaraine core as an acceptor unit end-capped with benz[cd]indole donor units functionalized with chiralaliphatic chains. Aggregates of these dyes in THF/water solvent mixture and thin films showed the absorbance beyond 1000 nm.
저자 Pongphak Chidchob, Joon Hak Oh
소속 Seoul National Univ.
키워드 squaraine; near-infrared; aggregates; chiral
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