화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 봄 (04/05 ~ 04/07, 대전컨벤션센터)
권호 42권 1호
발표분야 Innovative Carbon Materials for Industrial Applications
제목 Carbonization of Pyropolymers and Pyroproteins at High Temperature
초록 When polymers are heated in an inert atmosphere to temperature above 300 °C they lose much of their non-carbon content as gases and change to forms of carbon. This process is termed carbonization. The process by which the non-carbon content is thereafter eliminated is not complete until heat-treatment temperatures exceed 1000 °C. Below this temperature, the materials have intermediate properties between polymer and carbon and are termed pyropolymers. Here, we examined changes in the structural and chemical configurations of β-sheet structured proteins (pyroproteins) above the thermal degradation temperature (T>300 °C). We found that the β-sheet structure of the proteins was not destroyed, even during the rapid weight loss induced by thermal degradation. Subsequently, the β-sheet structure transformed to an sp2 carbon hexagonal structure by heating to 2800 °C.
저자 조세연1, 윤영수2, 진형준1
소속 1인하대, 2강원대
키워드 Carbonization; Graphitization; pyropolymers; pyroproteins
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