화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-고분자
제목 AFM based Nanoscratch Self-healing Studies of Urea-acrylate Copolymer Crosslinkings Composed of Hindered Urea Bonds
초록 Self-healing polymers (SHPs) have been used in industries given their prolonged shelf-life and lower manufacturing costs. Polymers with urea bonding are important materials in people's daily life due to their recyclability. When these urea bonded polymers are made in the form of SHPs, they impose excellent properties to the polymer including high strength, tremendous elasticity, and chemical resistance. Hindered Urea Bond (HUB) has been studied because of the reversible bond which enables the polymer to undergo multiple scratch healing. In this study HUB is incorporated in urea-acrylate copolymer by a covalent bond formed between bulky amine group and isocyanate moiety. Atomic force microscopy (AFM) was utilized for executing nano-scratches on the polymer surface and the healing process was monitored by the morphological changes at nanoscale.
Acknowledgement: The authors are very grateful for financial support from the National Research Foundation of Korea (Grant No.20201I1A304491)

 
저자 Sana Ahmed, 정인우, 이향무
소속 경북대
키워드 AFM; Hindered Urea Bond; Self-healing polymer
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