| 학회 | 한국고분자학회 |
| 학술대회 | 2004년 가을 (10/08 ~ 10/09, 경북대학교) |
| 권호 | 29권 2호, p.209 |
| 발표분야 | 고분자 구조 및 물성 |
| 제목 | LDOT-type A-b-B Copolymers from PS and Poly(n-alkyl methacrylate): Ethyl and n-Butyl Methacrylates as B-block |
| 초록 | As our continuing efforts to investigate the origin of LDOT behavior in homologous polystyrene-b-poly(n-alkyl methacrylate) (PS-b-PAnMA) copolymers, we perform a RPA and the corresponding fluctuation corrections analyses on A-b-B diblock copolymers in the case of poly(ethyl methacrylate) and poly(n-butyl methacrylate) as B-block. It is assumed that certain specific interactions are the driving force of the LDOT behavior. We attempt to offer a unified picture governing the phase behavior and the pressure responses of various thermodynamic transitions of the LDOT-showing PS-b-PAnMA copolymers. It will be shown that both fluctuation effects and compressibility are of great importance in elucidating the observed behavior of those copolymers. |
| 저자 | 정재윤1, 정진우2, 조준한1 |
| 소속 | 1단국대, 2고분자공학과 |
| 키워드 | PS-b-PEMA; PS-b-PnBMA |
