화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-고분자
제목 Both Highly Efficient and Mechanically Robust Polymer Solar Cells with Polymer Acceptor Additive Incorporation
초록 The authors report an polymer solar cell (PSC) system with 10% of power conversion efficienies (PCEs) and 30% of the entire device stretchablility, by employing high molecular weight (MW) polymer aceptor (PA) additives into highly efficient PSC system. Intiguingly, the binary PSC system showed ultra-high PCE of 15.42% without PA additive, and the PCE is maintained up to 13.97% with incorporating 30% of the additive in the PSC fabrication. We note the engineering crack onset strain (COS) sharply increases with loading of the PA additives, showing 6-fold increase from 2.21 at the blend without the additive to 11.93% with 30% of the PA loading. We revealed both the PCE maintanence and the skyrocketed mechanical robustness with loading of the PA additive are mainly attributed to the formation of chain entanglement and tie molecules due to long PA chains.
저자 김형준, 이진우, 김범준
소속 KAIST
키워드 polymer solar cell; mechanical property; polymer acceptor
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