화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 가을 (10/24 ~ 10/25, 한양대학교)
권호 9권 2호, p.2526
발표분야 열역학
제목 Isothermal Vapor-Liquid Equilibria for Alkane+Alkanol System near Critical Region
초록 Isothermal Vapor-Liquid Equilibrium data for the binary Alkane+Alkanol system were measured near the critical temperatures using a two-phase recirculating equipment with the view cell. Critical pressure was also determined from the critical opalescence of the mixtures. This mixture is shown very nonideal behavior due to the association of alcohol. The experimental data were correlated by the Peng-Robinson-Stryjek-Vera (PRSV) equation of state combined with the NRTL model and the Wong-Sandler mixing rule and Multi-Fluid Nonrandom Lattice Fluid with Hydrogen Bonding(MF-NLF-HB). We also calculated the critical points.
저자 오병철, 김영대, 김화용
소속 서울대
키워드 Vapor-Liquid Equilibria; Critical; alcohol
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