| 학회 | 한국공업화학회 |
| 학술대회 | 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 20권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Facile synthesis of polyfunctionalized m-terphenyl derivatives via mild-base benzannulation for UV filter applications |
| 초록 | Terphenyls are ubiquitous in nature and possess a plethora of biological activities. In addition, their conjugated π-systems result in unique electronic and optical properties employed in wide range of organic materials. Herein, we report a transition-metal-free benzannulation to access polyfunctionalized m-terphenyls starting from 3-formylchromones and 1,3-diaryl-2-propanones. This approach proceeds via domino Knoevenagel/intramolecular Michael addition/ring opening/aromatization. As an extension of this protocol, the synthesized m-terphenyl derivatives were evaluated as potent UV-filters. 1.T. Ishida, W. Mizutani, H. Azehara, K. Miyake, Y. Aya, S. Sasaki and H. Tokumoto, Surf. Sci., 2002, 514, 187. 2.(a) D. A. Dickie, A. Y. C. Chan, H. Jalali, H. A. Jenkins, H.-Z. Yu and J. A. C. Clyburne, Chem. Commun., 2004, 2432;(b) G. Yu, J. Gao, J. C. Hummelen, F. Wudl and A. J. Heeger, Science, 1995, 270, 1789;(c) F. Garnier, R. Hajlaoui, A. Yassar and P. Srivastava, Science, 1994, 265, 1684. |
| 저자 | 타말고라뮤엘존, 이용록 |
| 소속 | 영남대 |
| 키워드 | m-terphenyls; benzannulation; UV filter |
