화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 봄 (04/25 ~ 04/26, 순천대학교)
권호 9권 1호, p.1130
발표분야 촉매/반응공학
제목 Selective Catalytic Reduction (SCR) of Lean NOx using Hydrocarbon by Plasma Enhanced Catalysis over Nano-Size Gold Catalyst Supported on Alumina
초록 Nano-sized gold catalysts supported on alumina were prepared and applied to the lean DeNOx reaction by plasma-enhanced catalysis. The average size of metallic gold particles estimated by dark field TEM analysis was 4.5 nm. The plasma-Au/Al2O3 system showed an improved DeNOx activity at low temperatures below 250℃. In case of plasma-2.0wt%Au/Al2O3, NOx conversion was about 40% and N2 yield was 10~30% at 100~250℃. The NOx reduction activity to N2 using hydrocarbon reductant at this temperature range has not been reported yet. This low-temperature DeNOx activity seems to be caused by the increase of Au - alumina interface due to the formation of nano-sized Au particles, which facilitated plasma-activated NO2 and hydrocarbon being adsorbed on the metallic Au and alumina, respectively, migrated and then reacted with each other.
저자 이관영1, 이대원2, 류재홍2, 정동훈2, 이형상3, 전광민3
소속 1고려대, 2(주)블루플래닛, 3연세대
키워드 SCR; NOx; Plasma; Catalysis; Nano; Gold; Alumina
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