| 학회 |
한국공업화학회 |
| 학술대회 |
2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터) |
| 권호 |
15권 1호 |
| 발표분야 |
환경.에너지 |
| 제목 |
Preparation and Characterization of Polybenzimidazole-PolybenzoxazineMembranesfor Polymer Electrolyte Membrane Fuel Cell (PEMFC)at High Temperature |
| 초록 |
New polybenzimidazole (PBI) membranes cured with thermosetting resins, polybenzoxazine (PBOA), as a membrane matrix was prepared for high temperature PEMFCs. The obtained membranes formed pseudo-semi-interpenetrating polymer network (IPN) of thermosetting-thermoplastic polymers, which was supported by 2D diffusion ordered spectroscopy (DOSY) NMR, glass transition temperature, and chemical stability. The membranes exhibited proton conductivity in the range of 0.08 to 0.13 S cm-1, operating voltage of 0.71 V @ 0.2 A cm-2 at 150 oC, and much slower performance decay rate. |
| 저자 |
고태윤1, 김성곤1, 최성우2, 김기현2, 전우성2, 박정옥2, 장혁2, 이종찬1
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| 소속 |
1서울대, 2삼성종합기술원 |
| 키워드 |
Fuel cell; Membrane; Polybenzimidazole; Polybenzoxazine
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| E-Mail |
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