화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 분자전자 부문위원회 II
제목 Synthesize and characterization of conjugated polymers based on chlorinated isoindigo for organic electronic.
초록 Organic electronics have attracted tremendous interest due to their solution processability and mechanical flexibility. Research on new semiconducting materials becomes more important to improve performance of organic electronic devices. One of the useful methods is introducing halogen atoms to molecular structure. This strategy can enhance electron mobility and ambient stability due to lower HOMO and LUMO energy levels caused from strong electron-withdrawing property of halogen atoms. Among others, chlorine atom can be easily applied by simple modification into polymer molecules compared to fluorine atom. Also, chlorinated polymers showed comparable device performance with fluorinated polymers. In this study, alternating copolymers were synthesized by using isoindigo and different donor moieties, bithiophene and thienylenevinylene, via Stille polymerization. We characterized these polymers and fabricated organic thin film transistor (OTFT) and organic photovoltaic device(OPV).
저자 박종진, 김영아, 이승훈, 김증은, 김주환, 김동유
소속 광주과학기술원
키워드 conjugated polymer; OTFT; OPV
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