| 초록 |
Ultra-thin polymer films containing metal/metal complex have been prepared by vacuum codeposition of metal/metal complex and organic monomer or macromolecular prepolymer onto the substrate to achieve not only the individual dispersion of metal atoms/metal complex molecules in the polymer matrix but also to obtain ultra-thin polymer films. In the plasma polymerization cobalt powder/cobalt(II) meso-tetraphenylporphyrin(CoTPP), which is capable of binding oxygen molecule, and trans-2-butene were used as comonomers to make metal/metal complex containing plasma polymer films. The metal loading of 50% was achieved and the resulting films had a strong capability of reversibly binding oxygen, which might indicate that the molecule-scale dispersion of chemically reactive metal complex was obtained in the highly crosslinked plasma polymer films. |
