| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 | 30권 2호 |
| 발표분야 | 기능성 고분자 |
| 제목 | Preparation of aromatic diacrylates containing phosphine oxide moiety in organic-inorganic sol-gel matrix for holographic recording |
| 초록 | The photopolymerizable films of aromatic diacrylic monomer containing phosphine oxide moiety in organic-inorganic sol-gel matrix were successfully photopolymerized by a 532 nm laser. The rate of photopolymerization and conversion of double bond in acrylic monomer were monitored by photo-Infrared spectroscopy (photo-IR) and photo-differential scanning calorimetry (photo-DSC). The amounts of a precursor of sol-gel solution and acrylate monomers were optimized to prepare the photopolymer films containing high diffraction efficiency. Fabricated photopolymer films could be thicker than 200 μm and their holographic recording achieved high diffraction efficiency (＞93%) and low shrinkage (＜0.5%). Grating image of the photopolymerized film and application to 3D recording media are in progress. fig.1. Diffraction efficiency photopolymer films depending on the amount of a sol-gel precursor (a) and monomer (b) |
| 저자 | 장유미, 한미정 |
| 소속 | 한국화학(연) |
| 키워드 | Photopolymer; Holographic recording; Sol-gel; Diffraction efficiency |
