| 학회 |
한국고분자학회 |
| 학술대회 |
2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 |
30권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis of PE-b-PMMA through a Combination of Ethylene Polymerization with Chain Transfer to Aluminum and Atom Transfer Radical Polymerization |
| 초록 |
Block copolymers of linear polyethylene(PE) and polymethylmethacrylate(PMMA) were synthesized through a combination of ethylene polymerization with chain transfer to aluminum and atom transfer radical polymerization(ATRP). Selective chain transfer reaction in the ethylene polymerization by a sterically bulky metallocene catalyst and MAO produced an aluminum-terminated polyethylene. The aluminum-terminated polyethylene was oxidized using oxygen, followed by hydrolysis to provide a hydroxy terminated polyethylene(PE-OH). The molecular weight of PE-OH was controlled by the concentration of trimethylaluminum. The PE-OH was converted into a polyethylene macroinitiator, and ATRP of MMA with the polyethylene macroinitiator produced block copolymers of PE and PMMA. |
| 저자 |
전만성, 김상율
|
| 소속 |
한국과학기술원 화학과 (BK21) |
| 키워드 |
Ethylene; MMA; Polymerization; Aluminum; ATRP
|
| E-Mail |
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