| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
The characterization and application of polymerized hydroxyethyl acrylate and methacrylate family |
| 초록 |
Methylmethacrylate(MMA)and butylmethacrylate (BMA) are two kind of methacrylate family members. In this paper, 2-hydroxyethyl acrylate(HEA) were used to copolymerized with MMA and BMA to form two kinds of thermo-sensitive amphiphilic polymers: P(HEA-MMA)s and P(HEA-BMA)s. The 1H NMR spectrum of P(HEA-MMA) and P(HEA-BMA) in D2O was obtained . The optical density of P(HEA-MMA) and P(HEA-BMA) solution began to increase around 37 ℃, possibly due to the thermal collapse of the copolymer chains.. The air /water interfacial tension of P(HEA-MMA) and P(HEA-BMA) solution were increased by the content of the hydrophobic co-monomers increased.The mean diameter of the micelle of P(HEA-MMA)s by DLS and that of the micelle of P(HEA-BMA)s changed depends on temperature change. TEM photos of P(HEA-MMA) micelles and P(HEA-BMA) were taken to observe the size and the shape of micelles. |
| 저자 |
이주협, 장홍, 김진철
|
| 소속 |
강원대 |
| 키워드 |
polymerized hydroxyethyl acrylate; methacrylate
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| E-Mail |
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