| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Improvement in photovoltaic performance induced by increased crystallinity of Poly(3-hexylthiophene) |
| 초록 |
We suggested a novel approach to enhancing the crystallinity of P3HT in a P3HT:PC61BM blend via self-assembly promoted by a thiophene-based all-conjugated amphiphilic block copolymer. The crystallinity of the block copolymer exceeded the crystallinity of the P3HT alone due to the packing effects caused by repulsion among the hydrophobic hexyl and hydrophilic ethylene glycol oligomer side chains. The packing effects induced by the hydrophilic ethylene glycol oligomer side chains were expected to become significant in a P3HT:PC61BM mixture upon the addition of small amounts of the block copolymer. This led to the formation of a higher-order structure with enhanced P3HT crystallinity, even in the P3HT:PC61BM blend. |
| 저자 |
손성윤1, 임민정2, 이강영1, 박태호1
|
| 소속 |
1포항공과대, 2LG생활건강 |
| 키워드 |
Crystallinity; Organic solar cells; All-conjugated amphiphilic block copolymer
|
| E-Mail |
|
