화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 분자전자 부문위원회 II
제목 SYNTHESIS AND CHARACTERIZATION OF LiFSI DERITATIVE CONTAINING FLUOROSULFONYL ESTER LITHIUM SALT FOR LI-ION BATTERIES
초록 Lithium-ion batteries have gained an unprecedented importance in the energy storage of portable devices such as cell phone, and tablet personal computer in the last several years. Our purpose in the present work is to synthesize a new electrolyte based on fluorosulfonyl isocyanate that can be used in lithium-ion battery. The most popular subject Lithium bis(fluorosulfonyl)imide (LiFSI) electrolyte salt has a thermal stability and a high ionic conductivity. We synthesized a new type of electrolyte having a functional group of fluorosulfonyl imide like LiFSI that can more effectively provide lithium ions. Isocyanate was reacted with allyl alcohol and created a ester form which can make the structure to increase further portion of lithium ions. The resulting electrolytes were characterized by FTIR, 1H NMR spectroscopy and thermogravimetric analysis (TGA). The ionic conductivity of FSE form was compared by LiPF6.
저자 김환기, 류태욱, 스트라다사부찬드라, 이순호, 하재성
소속 건국대
키워드 Lithium-ion batteries; electrolytes; Isocyanate; Ester
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