학회 |
한국화학공학회 |
학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
권호 |
15권 1호, p.470 |
발표분야 |
에너지 |
제목 |
다공성 고분자 전해질의 전기화학적 특성평가 |
초록 |
Polyurethane was synthesized by polyaddition of polytetra methylene ether glycol(PTMEG) and ethylene glycol(EG) with 4,4'-methylenebis(phenyl isocyanate)(MDI) and had been used of DMF as a solvent. Polyurethane solution was prepared by varying the composition of the DMF. And then, that was casted on Teflon sheet. Micro-porous polyurethane films were prepared by phase inversion, and their properties were characterized with Fourier transform infrared spectroscopy(FT-IR) and scanning electron microscope(SEM). Polyurethane polymer electrolytes were prepared by soaking the porous films in 1M LiCF3SO3-PC, and investigated ionic conductivity and decomposition voltage. The ionic conductivity of the 30% polyurethane film with LiCF3SO3-PC was 1.2×10-4 S/cm at room temperature. |
저자 |
최재원1, 안주현2, 신초롱1, 김종선2, 박진우1, 안효준2, 류호석1, 김익환3
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소속 |
1경상대, 2IT용 에너지 저장 및 변환연구센터, 3아이큐브 사업단 |
키워드 |
polyurethane; electrolyte; microporous; phase inversion
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E-Mail |
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