화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.470
발표분야 에너지
제목 다공성 고분자 전해질의 전기화학적 특성평가
초록 Polyurethane was synthesized by polyaddition of polytetra methylene ether glycol(PTMEG) and ethylene glycol(EG) with 4,4'-methylenebis(phenyl isocyanate)(MDI) and had been used of DMF as a solvent. Polyurethane solution was prepared by varying the composition of the DMF. And then, that was casted on Teflon sheet. Micro-porous polyurethane films were prepared by phase inversion, and their properties were characterized with Fourier transform infrared spectroscopy(FT-IR) and scanning electron microscope(SEM). Polyurethane polymer electrolytes were prepared by soaking the porous films in 1M LiCF3SO3-PC, and investigated ionic conductivity and decomposition voltage. The ionic conductivity of the 30% polyurethane film with LiCF3SO3-PC was 1.2×10-4 S/cm at room temperature.
저자 최재원1, 안주현2, 신초롱1, 김종선2, 박진우1, 안효준2, 류호석1, 김익환3
소속 1경상대, 2IT용 에너지 저장 및 변환연구센터, 3아이큐브 사업단
키워드 polyurethane; electrolyte; microporous; phase inversion
E-Mail
원문파일 초록 보기