화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 Electrochemical Behaviors of Poly(ethylene) Oxide Electrolytes Containing Alkyl-imidazolium-type Salts
초록 Rechargeable and high-specific-energy lithium batteries are promising power sources for modern portable electronic devices and electric vehicles. However, the severe reactivity of lithium ion electrodes greatly limits the choice of usable electrolytes and incurs safety problems for the commercialization of rechargeable batteries. Solid polymer electrolytes for lithium batteries have many advantages, although their conductivity at room temperature is usually too low to applicable. In this work, the composite electrolytes based on poly(ethylene oxide) (PEO) and alkyl-imidazolium salts as room-temperature molten salts were prepared to study the additional salt effects on the structural and electrochemical properties. By using a large volume-size and molten salt rather than conventional salts, the modification of ion transport behaviors could be expected. As a result, the relating physical and electrochemical properties had been modified.
저자 김 석1, 이재락1, 박수진2
소속 1한국화학(연), 2인하대
키워드 electrochemical behaviors; composite electrolytes; micro-structure; molten salts
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