| 학회 |
한국화학공학회 |
| 학술대회 |
2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 |
25권 1호, p.996 |
| 발표분야 |
촉매 및 반응공학(Catalysis and Reaction Engineering) |
| 제목 |
Thin g-C3N4 Shell wall Grafted Monodispersed CuS Nanograin loaded free-standing Electrospun Carbon Nanofibers as Self-supported Visible Photocatalystic Web |
| 초록 |
Hierarchical 1D platform of g-C3N4 loaded free standing CuS-Carbon nanofibers (NFs) with high visible photocatalytic activity has been successfully synthesized by combining the electrospinning process followed by the thermal influences with controlled chemical vaporization. To induce the monodispersity of the Cu grains with high conductivity of carbon fibers, GO has induced with the spinning precursor leads to avoid the aggregation of Cu ions in high-temperature carbothermal process. Further annealed CuO nanograins were modified into CuS nanograins through the controlled sulfidation in the hydrothermal conditions using thioacetamide as a sulfur source. In vapor phase condition thin layer of g-C3N4 were decorated as a shell finish over the free-standing CuS-Carbon fibers and leads the construction of ternary phase heterostructure in a free-standing web form. Catalytic results indicated that the efficiency of the ternary NF system (Carbon/CuS/g-C3N4) was effectively improved after g-C3N4 loading which is nearly 2.1 times faster than the pristine Carbon-CuS NFs over the pharmaceutical pollutant (tetracycline) under visible irradiation. |
| 저자 |
박범준1, Ranjith Shanmugam2, 한영규2, 허윤석1
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| 소속 |
1인하대, 2동국대 |
| 키워드 |
촉매 |
| E-Mail |
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| 원문파일 |
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