| 초록 |
Polymerizable monomer, 2-(azidomethyl)-2,3-dihydrothieno[3,4-b][1,4]dioxine (EDOT-MZ) was synthesized. The polymer from the EDOT-MZ derivatives was deposited by both electrochemical and vapor phase polymerization method. FT-IR spectroscopy confirmed the photo-cross linking originated from the azide functional group. Micro scale conductive photo patterns were generated by UV exposure onto PEDOT-MZ film through a photomask. The electrical and optical properties of the PEDOT-MZ were examined by cyclic voltammetry and UV-vis spectroscopy. The refractive index of polymer film in each different potential was calculated by diffraction experiment. Patterned electrochromic cells were made by the direct photo-patterning method that can be easily applied in organic electrodes or electrochromic devices. |
