| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
(촉매) 기능성 촉매 합성 및 응용 |
| 제목 |
Heterogeneous Catalysts for Synthesis of Tricyclopentadiene Isomer from Dicyclopentadiene |
| 초록 |
Tricyclopentadiene has been used as a high-energy-density fuel because it has a high calorific value and high density. Tricyclopentadiene can be produced via diels-alder reaction of dicyclopentadiene. Because freezing point and viscosity of endo-type tricyclopentadieneare is higher than those of exo-type tricyclopentadiene, it is need to convert to exo-type by isomerization. In this study, we used zeolites as a catalyst in synthesis of tricyclopentadiene from dicyclopentadiene. In addition, a hybrid material composed of microporous and mesoporous material prepared from commercial zeolites was evaluated as a catalyst for oligomerization of diicyclopentadiene. The hybrid material composed of microporous and mesoporous material shows high reaction activity and selectivity in a dicyclopentadiene oligomerization which can be attributed to the large pore size as well as moderate acidity. |
| 저자 |
전종기1, 임진형1, 유용인1, 한정식2
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| 소속 |
1공주대, 2국방과학(연) |
| 키워드 |
Tricyclopentadiene; 불균일계 촉매
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| E-Mail |
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